The Mole

The mole is a specific number of elementary entities (a clever–sounding name for what is, for our purposes, atoms) of a chemical. The number of atoms in a mole is 6.022 cross times 1023, which is called the Avogadro number. Avogadro was an Italian gentleman who established that the volume of a gas (at a given pressure and temperature) is proportional to the number of atoms or molecules regardless of the nature of the gas.

Because atoms have a known mass, a mole of a substance also has a known mass. This mass is based on the atomic mass, which is also the atomic number of the substance. The atomic mass of carbon is 12, so a mole of carbon has a mass of 12 g. For molecules, we add the atomic masses together. For example, the atomic mass of oxygen is 16, and molecular mass of an oxygen molecule (O2) is 16 x 2 = 32, so one mole has a mass of 32 g.

So 100 g of oxygen is:

fraction numerator 100 space g space o x y g e n over denominator begin display style fraction numerator 32 space g over denominator m o l end fraction end style end fraction space equals space 3.125 space m o l space o x y g e n

When we use mole in calculations, we drop the e so it is written as mol. Like g and m, the mole is an SI unit and can have prefixes for orders of magnitude above and below 10 (as we saw in the figure earlier). A kmol is 1,000 moles and is the mole equivalent to kg and km.

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