Conduction

As we previously learned, when heat is transferred between two objects in contact with one another, we call it conduction.

The steady state rate of heat transfer through a single layer of material is defined by Fourier’s law, represented by the equation:

q over A space equals space k space fraction numerator increment T over denominator increment x end fraction

Where

q is the required amount of heat flow, measured in J s-1  (W)

A is the surface area, measured in m2

k is the thermal conductivity, measured in W m-1 °C-1

∆T =  T2 − T1 is the temperature drop across the layer, measured in °C

∆x =  x2 − x1 is the thickness of the layer starting at x1 and ending at x2, measured in m.

Let us have a closer look at one of these components – thermal conductivity.

This equation results in the heat transfer rate in units of energy rate per surface area, or W m-2. It is often reported and used with area on the other side of the equation as seen below. When the surface area is known, this equation should be used which results in the heat transfer rate in units of W.

q space equals space k A space fraction numerator increment T over denominator increment x end fraction

Thermal conductivity

Thermal conductivity, k, is a physical property of a material which describes how easily heat will flow through it. The SI unit for thermal conductivity is W m-1 °C-1. Here are some thermal conductivity values for common heat transfer materials:

Stainless steel: 17 W m-1 °C-1

Mild steel:  45 W m-1 °C-1

Copper: 380 W m-1 °C-1

Silver: 415 W m-1 °C-1

In general, the higher the thermal conductivity of a material, the better it is at transferring heat. Based on the values listed above, we can see that copper allows heat to transfer more effectively than stainless steel.

When a material is good at conducting heat, we call that material a conductor. When a material is resistant to or not very good at conducting heat, we call that material an insulator.

Some examples of good conductors in a brewery are steel and copper. Some examples of good insulators in a brewery are water, plastic, air, and mineral wool – which is found in the insulation surrounding pipes. A common everyday example which illustrates conduction and insulation properties is a frying pan. The pan itself is typically made from a good conductor metal like steel or iron, which allows heat to travel from the stove through the pan and to the food. The handle is usually coated with a plastic that will not allow heat to travel through it, so we can hold it while cooking without burning ourselves.

It should be clear now that if we want heat to travel through a material and to heat another material, then all the materials need to be good conductors and have a high thermal conductivity. However, if we want to keep heat contained and reduce the loss of heat to the atmosphere, then we require a good insulator.

Next, we will look at two different scenarios where Fourier’s law can be applied.

Fourier’s law applied to a single layer

The figure below shows a simple example of conduction through a single layer.

Figure: Conduction through a single layer

Figure: Conduction through a single layer

Here, we have heat flow through a single layer, perhaps a stainless steel plate. At the beginning of the plate at x1 we have temperature T1. At the end of the plate at x2 we have temperature T2. Fourier’s law can be used to calculate q, the rate of heat transfer through the plate.

Let us assume that T1 is 65°C, T2 is 50°C, and the thickness of the stainless steel plate is 4 cm and a surface area of 1.5 m2. If the thermal conductivity of stainless steel is 17 W m-1 °C-1, what is the rate of heat flow through the plate?  To determine this, recall Fourier’s law for steady state rate of heat transfer by conduction:

q over A space equals space k space fraction numerator increment T over denominator increment x end fraction

We can simply enter the values. 

q over A space equals space 17 space cross times space fraction numerator 50 space minus space 65 over denominator 0.04 end fraction space equals space minus 6 comma 375 space W space m to the power of 2 to the power of negative 1 end exponent end exponent

Note that the answer is negative because the heat is being lost, this is evident because the temperature decreases from one side of the plate to the other.

If we know the entire area of the plate, we can also calculate the heat flow rate in W. Let us assume the area of the plate is 1.5 :

q equals negative 6 comma 375 space cross times space 1.5 space equals negative 9 comma 563 space W

Fourier’s law applied to multilayer systems

In the example above, we had one single layer to account for. We calculated the heat flow through the plate given the one single layer of resistance. Thermal resistance is a measure of a temperature difference by which an object or material resists heat flow. The resistance is dependent on the material thermal conductivity, k, the plate thickness, B, and the area of the heat transfer, A. Mathematically we can write this as:

R subscript t space equals space fraction numerator increment x over denominator k space A end fraction

If we substitute this formula for thermal resistance into the Fourier equation, it will look like this:

q space equals space fraction numerator capital delta T over denominator R subscript t end fraction

For each layer of additional resistance, we have an additional resistance term. The figure below shows a three-layer system.

Figure: Conduction through a three-layer system

Figure: Conduction through a three-layer system

Here, we have three layers of resistance with different thicknesses, thermal conductivity, areas, and initial and final temperatures. To calculate the heat flow through the entire system, we can modify Fourier’s law:

q space equals space fraction numerator capital delta T subscript 1 over denominator R subscript t subscript 1 end fraction space equals space fraction numerator capital delta T subscript 2 over denominator R subscript t subscript 2 end fraction space equals space fraction numerator capital delta T subscript 3 over denominator R subscript t subscript 3 end fraction

Where

capital delta T subscript 1 space equals space T subscript 1 space minus space T subscript 2

capital delta T subscript 2 space equals space T subscript 2 space minus space T subscript 3

capital delta T subscript 3 space equals space T subscript 3 space minus space T subscript 4

R subscript t subscript 1 space equals space fraction numerator B subscript 1 over denominator k subscript 1 space A subscript 1 end fraction

R subscript t subscript 2 space equals space fraction numerator B subscript 2 over denominator k subscript 2 space A subscript 2 end fraction

R subscript t subscript 3 space equals space fraction numerator B subscript 3 over denominator k subscript 3 space end subscript A subscript 3 end fraction

In a brewery, this example is seen in a pipe with insulation. Adding an additional layer of insulating material around a pipe adds another layer of resistance for heat to flow out of or into the pipe.

Insulation increases thermal efficiency by reducing the heat that is lost or absorbed.

As heat flows radially through a pipe, Fourier’s law needs to be modified to account for the geometry of the pipe.

Fourier’s law applied to pipes

Heat transfers from hot to cold in the direction that is normal to the heat source. Normal means in the direction that makes a 90° angle to the surface. In a pipe, heat transfers from the centre out towards the surface of the pipe. Consequently, temperature varies in a radial direction, i.e. if the fluid is hot, the hottest part is in the centre and it gets cooler towards the outside of the pipe. The figure below shows the temperature gradient in an insulated pipe. 

Figure: Heat flow out of an insulated pipe

Figure: Heat flow out of an insulated pipe

Let us examine the figure above.

  • The area A is the actual pipe.

  • The inner radius of the pipe is r1, which is the length from the centre of the pipe to its inside wall.

  • The outer radius of the pipe is r2, which is the length from the centre of the pipe to its outside wall.

  • T1 is the temperature of the fluid or gas inside the pipe.

  • The area B is the insulation with temperature T2.

  • The outer radius of the insulation is r3, which is the length from the inside of the pipe to the outside of the insulation.

  • Lastly, the temperature on the outside of the pipe is T3.

If there is hot liquid, say wort, flowing through a pipe, there will be some heat loss from the liquid through the pipe walls and into the atmosphere. Recall from earlier that the general equation for heat flow by conduction is Fourier’s law:

q space equals space k A space fraction numerator increment T over denominator B end fraction

The area of heat transfer in a pipe is the log mean area of the pipe, defined as: 

A subscript L M end subscript space equals space fraction numerator left parenthesis A o space minus space A i right parenthesis over denominator ln space begin display style open parentheses fraction numerator A o over denominator A i end fraction close parentheses end style end fraction space equals space 2 pi L space fraction numerator left parenthesis r subscript 2 space minus space r subscript 1 right parenthesis over denominator ln space begin display style open parentheses r subscript 2 over r subscript 1 close parentheses end style end fraction

Where L is the length of the pipe, Ai and Ao are the inside and outside surface areas and r1 and r2 are, respectively, the inner and outer radius of the pipe r1 r2.

The thickness of the pipe is the outer radius minus the inner radius, or r2 − r1.

If we enter the log mean area and the pipe thickness into the Fourier equation, we get the following for the flow of heat through a pipe wall:

q space equals space fraction numerator k space 2 pi space L space increment T over denominator ln space open parentheses r subscript 2 over r subscript 1 close parentheses end fraction

Where

q is the heat flow in the pipe, measured in J s-1 (W)

k is the thermal conductivity of the pipe material, measured in W m-1 °C-1

L is the length of the pipe, measured in m

∆T =  T1 − T2 is the temperature drop across the layer, measured in °C

r2 is the outside radius of the pipe, measured in m

r1 is the inside radius of the pipe, measured in m.

If the pipe is insulated, an extra step is necessary because we need to account for the heat resistance of the insulation as well as the piping material. The equation for heat loss through an insulated pipe is:

q equals fraction numerator 2 pi L increment T over denominator begin display style fraction numerator ln space begin display style open parentheses r subscript 2 over r subscript 1 close parentheses end style over denominator k end fraction space plus space fraction numerator ln space begin display style open parentheses r subscript 3 over r subscript 2 close parentheses end style over denominator k subscript 3 end fraction end style end fraction

Where

r3 is the outside radius of the insulation, measured in m

k3 is the thermal conductivity of the insulation, measured in W m-1 °C-1.

Let us combine what we have learned about Fourier’s law into a worked example before we finish the lesson.

Fourier’s law example

Let us calculate the heat loss from a 3 m length of stainless steel pipe from the wort kettle to the whirlpool in a brewery.  The wort inside the pipe is 100°C. The temperature on the outside surface of the pipe is 93°C. The inside radius of the pipe is 5 cm and the outside radius is 5.8 cm.

First, we decide which equation to use. We are using a pipe without any layer of insulation, so we can use the following equation derived above:

q space equals space fraction numerator k space 2 pi space L space increment T over denominator ln space open parentheses r subscript 2 over r subscript 1 close parentheses end fraction

Recall that the thermal conductivity of stainless steel is 17 W m-1 °C-1. We need to convert the pipe radius from cm to m. There are 100 cm in 1 m, so the inner radius is 0.05 m and the outer radius is 0.058 m. The only thing left to do is to enter the values and calculate.

q space equals space fraction numerator 17 space cross times space 2 space cross times space pi space cross times space 3 space cross times space left parenthesis 93 space minus space 100 right parenthesis over denominator ln space open parentheses begin display style fraction numerator 0.058 over denominator 0.05 end fraction end style close parentheses end fraction space equals space minus 15 comma 113 space W

This number is negative because it is heat being lost or exiting the system.

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