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The Control of Oxidation Throughout the Brewing Process

So, how does the brewer control oxidation? There are several things they can do, from the choice of raw materials to the manipulation of processing conditions. Let us summarise these using a table.

Table. Process impacts on flavour instability

Process

Aspect

Control

Malt

LOX levels

Use LOX-less malt

Mash conversion

LOX levels

Mash in above 60°C to reduce LOX levels

Favour lower mash pH to reduce LOX levels

Decoction

Decoction oxygen pickup higher than single mash

Superoxide radical formation

Higher mash pH reduces radical formation

Raw materials

Use higher coloured malts containing antioxidant melanoidins

Use lower rice, maize – can be high in lipid

Vessel material of construction

Use stainless steel, Copper and iron catalyse ROS formation

Wort separation

Turbidity

Run brighter worts to give more yeast derived SO2 antioxidant

Weak worts collection

Avoid collecting as weak worts have increased lipid levels

Wort boiling

Boil time thermal damage

Longer boils are more thermally damaging

Boil volatile stripping

Rolling boil is more effective at volatile stripping thus better

Liquid adjuncts

Liquid adjuncts favour stable beer as they contain negligible lipids

Hops

Pellets contain more antioxidant polyphenols than extracts

Vessel material of construction

Use stainless steel, Copper and iron catalyse ROS formation

Whirlpool

Wort clarity

Clear worts promote SO2 production from yeast

Vessel material of construction

Use stainless steel, Copper and iron catalyse ROS formation

Wort cooling

Oxygen pickup

Correct level for yeast promotes health and carbonyl reduction

Fermentation

Yeast strain

Some strains are high SO2 producing

Cold break removal

Remove cold break to create brighter wort therefore more SO2 production by yeast

Warm maturation

Warm conditioning removes VDK’s

Vessel material of construction

Use stainless steel, Copper and iron catalyse ROS formation

Maturation

Oxygen pickup.

CO2 injection during transfer and sometimes in maturation vessel reduces oxygen

Vessel material of construction

Use stainless steel, Copper and iron catalyse ROS formation

Filtration

Metal pickup

Low iron kieselguhr better, KG free filtration (eg membrane), best

Polyphenol removal

PVPP removes protective polyphenols

Dissolved oxygen pickup

Latest designs packaging lines guarantee lower DO

pH

The higher the pH the lower the ROS produced.

Packaging

Dissolved oxygen pickup

Scavenging crown liners reduce DO

lightstruck reaction

Cans and kegs protect from lightstruck. Reduced hops offer significant protection. Bottle colour protection is best for brown, then green, and least protective, flint (clear) glass containers

Beer analysis

Dissolved oxygen content

Lower is better

SO2

Higher SO2 is better as staling aldehydes are bound

Warehouse

Lightstruck reaction

Avoid sunlight and damaging artificial light wavelengths

Temperature

Lower temperature retards oxidation

Stock rotation practices

Practice FIFO (first in, first out), not FILO (first in , Last out)

Temperature

Lower temperature retards oxidation

Distribution and outlets

Lightstruck reaction

Avoid sunlight, damaging artificial light wavelengths

Agitation of containers

Avoid where possible as oxygen is introduced into the liquid

Time

Store as short as possible

Stock rotation practices

Practice FIFO, not FILO

 

Temperature

Lower temperature retards oxidation

Inventory control

Shelf life

Best before date on package

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